Formation of organorhodium complexes via C-H bond activation of 1,3-di(phenylazo)benzene.

نویسندگان

  • Paramita Majumder
  • Suparna Baksi
  • Sarmistha Halder
  • Haregewine Tadesse
  • Alexander J Blake
  • Michael G B Drew
  • Samaresh Bhattacharya
چکیده

Reaction of a potential NCN-pincer ligand, viz. 1,3-di(phenylazo)benzene (L), with [Rh(PPh(3))(3)Cl] affords, via a C-H bond activation, an interesting dinuclear Rh(II) complex (1), and with RhCl(3)·3H(2)O affords a mononuclear Rh(III) complex (2) containing a catalytically useful Rh-OH(2) fragment.

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عنوان ژورنال:
  • Dalton transactions

دوره 40 20  شماره 

صفحات  -

تاریخ انتشار 2011